Following the Champions League round of 16 draw in Nyon, Arsenal have been drawn against defending champions Barcelona while Chelsea will play Paris St-Germain for the third consecutive season and Manchester City face Dynamo Kiev.
Arsenal last played Barcelona in the second round of the Champions League in 2011. The Gunners won the first leg at the Emirate Stadium 2-1 before losing the second leg, 3-1.
Arsenal have won only one of their seven Champions League games against Barcelona
Bundesliga champions Bayern Munich will take on Serie A counterparts and last season's European runners-up Juventus, who lost to the German giants 4-0 in the 2013 quarter-finals
The draw for the quarter-finals will be held on 18 March with the semi-final line-up drawn on 15 April.
The group runners-up will play the first leg at home.
Gent v Wolfsburg
Roma v Real Madrid
Paris v Chelsea
Arsenal v Barcelona
Juventus v Bayern
PSV v Atlético
Benfica v Zenit
Dynamo Kyiv v Man. City